Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds.

نویسندگان

  • Miguel Rubio
  • Andrés Suárez
  • Diego del Río
  • Agustín Galindo
  • Eleuterio Alvarez
  • Antonio Pizzano
چکیده

Square-planar ethylene rhodium derivatives bearing pincer diphosphite ligands have been prepared and characterized, they display a rare in-plane coordination which, based on DFT calculations, has been mainly attributed to steric effects.

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عنوان ژورنال:
  • Dalton transactions

دوره 4  شماره 

صفحات  -

تاریخ انتشار 2007